Most (all?) of the early ED lenses used ED glass on the front element, including the early ED telephotos for the AU-1 focus unit, and early AI and AIS ED telephotos. Nikon stated their ED glass was robust enough to be used on the front element, unlike the fluorite used by some competitors. However Nikon did recommend using large UV filters to protect the ED glass from damage.
In the mid 1980s Nikon upgraded a number of their earlier IF-ED telephotos, and among the changes, the front element was now protected by a permanent fixed front protection lens. Maybe due to feedback from professional, Nikon realised the ED glass was more vulnerable than first thought. Since then all big telephotos have had a front protection lens, or the ED glass was not used as the front element.