Birna is correct.
Your small glass plate was almost certainly a Lantern Slide which would have been used in a Magic Lantern projector.
It was normal practice to print a positive onto these glass slides from the original negative.
During my Photography course at Guildford College of Art, we had to learn how to do this.
In the mid 1950s one could still purchase the emulsion-coated 3.5" x 3.5" glass slides and their accompanying plain glass cover-slips. (European lantern slides were of a slightly different size)
After processing the Slide, you covered the emulsion side with the plain glass cover; then bound the edges with gummed black paper tape and added a white spot in one corner (so that the projectionist inserted the slide in the correct orientation).